Phosphate hideout in boilers
http://www.steamcycle.com/hideout.htm WebAug 22, 1994 · When a boiler's feedwater routinely meets such high purity standards, the internal chemical program of choice is normally a pH/phosphate control program (sometimes known as a coordinated or congruent phosphate control program), optionally together with a dispersant treatment.
Phosphate hideout in boilers
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WebThis phenomenon, known as "phosphate hideout," can make it difficult to maintain close control of the pH phosphate concentration. Both the magnitude of the phosphate hideout … WebUsually associated with low pH excursions Formation of nascent hydrogen (HO) at the boiler tube surface Hydrogen permeates the tube where it can react with Iron carbides to form methane gas Other hydrogen atoms to form hydrogen gas Gases collect at grain boundaries to increase pressure Microfissures occur within the material and weaken the tube
WebMar 15, 2015 · Phosphate hideout is characterized by the retention of phosphate in the boiler during conditions of high pressure and the subsequent release of phosphate when the pressure is reduced. The condition is most often reported in high-pressure units, e.g., 2,500 psi (17.24 MPa). WebAbstract. Sodium phosphates deposit on heat transfer surfaces from boiling solutions. This process of deposition, which is termed “hide-out”, was studied in a recirculating loop …
WebFIG. 13. Solubility of tri-sodium phosphate as a function of temperature. In high-pressure boilers, most of the phosphate added for pH and, if necessary, hardness control may … http://www.steamcycle.com/hideout.htm
WebHideout can occur with tri-sodium phosphate or when Na/PO4is more than 2.6 for boilers suffer from scale deposition, it also occurs when more phosphate is dosed to the boiler drum, that exceeds the equilibrium concentration.
Webthrough boilers, but because there are no separate superheaters, the sample is taken from the superheated steam prior to entering the turbine. Fig. 4 Silica versus permissible boiler pressure Silica (mgl-1) NaOH dosed boiler NH3 dosed boiler Permissible Boiler Pressure (bar) 80 100 110 120 130 140 150 180 3.6 3.2 2.8 2.4 2.0 1.6 1.2 0.8 0.4 0. redress number dod idWebThe minimum phosphate is 0.2 mg/L. PC(L) or Phosphate Continuum (Low) requires higher purity feedwater, but uses lower phosphate target ranges and minimizes the propensity for phosphate hideout. PC(H) or Phosphate Continuum (High) is the most forgiving program if there are upsets in boiler feedwater quality, but it does increase the propensity ... redress number for militaryWebMar 1, 2013 · Moreover, after restarting the boiler, several load changes was recorded. Load change is one of the main causes of phosphate hideout in which phosphate precipitates and consequently free caustic may form [13], [16]. Therefore, as a result of load changes and bulk phosphate hideout, boiler water analysis had shown unusual fluctuations. richman transmissionsWebPhosphate hideout is a phenom- enon that causes boiler water control difficulties. It is defined as the disappearance, by precipita- tion or absorption, of the ionic phosphate (PO4) species, in the boiler water under high heat transfer or high load conditions. When the high heat flux or high load condition is reduced, the rich man tormented in hellWebNov 1, 2015 · Boiler cleanliness must be maintained to reduce the risk associated with phosphate hideout. Use trisodium phosphates in place of mono- or disodium phosphates … rich man trickWebMar 15, 2015 · Phosphate hideout is characterized by the retention of phosphate in the boiler during conditions of high pressure and the subsequent release of phosphate when … rich mansion interiorWebMar 22, 2009 · Many U.S. electric utilities have converted their drum boilers to caustic treatment and eliminated problems such as phosphate hideout. This paper will discuss the basics of caustic treatment and present some case histories of successful operation in a caustic boiler water treatment regimen. richman tuchel leonard